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OCHEM 2 EC

Across
A nucleophilic addition of a carbanion or other nucleophile to an alpha-beta unsaturated carbonyl compound containing an EWG.
A reaction consisting of the enolate of a ketone or aldehyde and an alcohol resulting in an hydroxy carbonyl.
A reaction where the acid catalyzed elimination of water to result in a t-butyl methyl ketone.
An experimentation method of oxidation using a solution of chromium trioxide in diluted sulfuric acid.
The process by which one molecule is transformed into another molecule. Could be through enol or enolate intermediates.
Electrophilic substitution by a carbenium ion intermediate resulting in an alkylarene
A chemical equilibrium between the ketone or aldehyde and an enol (Alcohol).
An organic reaction forming an ether from an organohalide and alkoxide
An organic reaction used to convert aldehyde or ketone to an alkane using hydrazine, base and thermal conditions.
What kind of group creates a higher energy intermediate and decreases substitution rate.
A reaction where a primary or secondary alcohol is oxidized to an aldehyde or ketone.Using the reagents oxalyl chloride, DMSO and an organic base.
Down
A carbon-carbon bond forming reaction between two esters or an ester and another carbonyl compound in the presence of a strong base.
When a conjugated diene reacts with an alkene at positions 1 and 4 forming a cyclohexene ring.
A reaction involving a single step, a primary/secondary electrophile and aprotic polar solvents.
A reaction involving two steps, a carbenium ion intermediate, bulky bases, Zaitevs rule, and doesn't require a strong base.
A nucleophilic addition of phenoxide, sodium phenoxide to carbon dioxide resulting in salicylate. After acid workup resulting in salicylic acid.
This kind of nucleophile is usually large 3-5th row elements and undergo 1,4 addition.
When the Halide is added to the carbon atom with the greatest number of hydrogen atoms attached.
A reaction consisting of a Michael addition and an aldol condensation
This kind of nucleophile is usually small second row elements and undergo 1,2 addition.
An anion formed when an alpha hydrogen in an aldehyde or ketone is removed
When the Halide is added to the carbon atom with the least number of hydrogen atoms attached.
When some Elimination reactions give the least favored and least alkyl-substituted product.
A reaction involving a single step, no intermediate formation, bulky bases, Zaitevs rule, and require s a strong base.
What kind of bases are used for kinetic enolate formation
What kind of group stabilizes the intermediate and increases substitution rate.
An organic reaction used to convert an alpha,beta unsaturated ketone to an allylic alcohol using cerium trichloride sodium borohydride and an alcohol solvent.
A reaction involving two steps, a secondary/tertiary electrophile, protic polar solvents and has a carbenium ion intermediate.