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OCHEM 2 Extra Credit

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Across
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An experimentation method of oxidation using a solution of chromium trioxide in diluted sulfuric acid.
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This kind of nucleophile is usually small second row elements and undergo 1,2 addition.
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An organic reaction forming an ether from an organohalide and alkoxide
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A carbon-carbon bond forming reaction between two esters or an ester and another carbonyl compound in the presence of a strong base.
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Electrophilic substitution by a carbenium ion intermediate resulting in an alkylarene
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A nucleophilic addition of a carbanion or other nucleophile to an alpha-beta unsaturated carbonyl compound containing an EWG.
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This kind of nucleophile is usually large 3-5th row elements and undergo 1,4 addition.
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What kind of group stabilizes the intermediate and increases substitution rate.
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An anion formed when an alpha hydrogen in an aldehyde or ketone is removed
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A reaction where a primary or secondary alcohol is oxidized to an aldehyde or ketone.Using the reagents oxalyl chloride, DMSO and an organic base.
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A reaction involving a single step, no intermediate formation, bulky bases, Zaitevs rule, and require s a strong base.
Down
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A reaction consisting of the enolate of a ketone or aldehyde and an alcohol resulting in an hydroxy carbonyl.
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The process by which one molecule is transformed into another molecule. Could be through enol or enolate intermediates.
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A reaction where the acid catalyzed elimination of water to result in a t-butyl methyl ketone.
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When the proton added to the carbon atom with the greatest number of hydrogen atoms attached.
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A reaction involving two steps, a carbenium ion intermediate, bulky bases, Zaitevs rule, and doesn't require a strong base.
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A chemical equilibrium between the ketone or aldehyde and an enol (Alcohol).
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An organic reaction used to convert an alpha,beta unsaturated ketone to an allylic alcohol using cerium trichloride sodium borohydride and an alcohol solvent.
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What kind of group creates a higher energy intermediate and decreases substitution rate.
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When the proton added to the carbon atom with the least number of hydrogen atoms attached.
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An optically active carbonyl compound whose chiral centre is a hydrogen-bearing carbon at the beta position gradually loses its optical activity when its dissolved in an acidic or basic solution.
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What kind of bases are used for kinetic enolate formation
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A nucleophilic addition of phenoxide, sodium phenoxide to carbon dioxide resulting in salicylate. After acid workup resulting in salicylic acid.
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When some Elimination reactions give the least favored and least alkyl-substituted product.
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An organic reaction used to convert aldehyde or ketone to an alkane using hydrazine, base and thermal conditions.
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A reaction consisting of a Michael addition and an aldol condensation
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When a conjugated diene reacts with an alkene at positions 1 and 4 forming a cyclohexene ring.
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A reaction involving two steps, a secondary/tertiary electrophile, protic polar solvents and has a carbenium ion intermediate.
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A reaction involving a single step, a primary/secondary electrophile and aprotic polar solvents.